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Abstract A thermo‐time domain reflectometry (thermo‐TDR) sensor combines a heat‐pulse sensor with a TDR waveguide to simultaneously measure coupled processes of water, heat, and solute transfer. The sensor can provide repeated in situ measurements of several soil state properties (temperature, soil water content, and ice content), thermal properties (thermal diffusivity, thermal conductivity, heat capacity), and electromagnetic properties (dielectric constant and bulk electrical conductivity) with minimal soil disturbance. Combined with physical or empirical models, structural indicators, such as bulk density and air‐filled porosity, can be derived from measured soil thermal and electrical properties. Successful applications are available to determine fine‐scale heat, water, and vapor fluxes with thermo‐TDR sensors. Applications of thermo‐TDR sensors in complicated scenarios, such as heterogeneous root zones and saline environments, are also possible. Therefore, the multi‐functional uses of thermo‐TDR sensors are invaluable for in situ observations of several soil physical properties and processes in critical zone soils.